Synthesis and crystal structure of a new Fe(II) α-dioximate with triazine
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CIOBĂNICĂ, Olga; BOUROSH, Pavlina; BOLOGA, Olga; BULHAK, Ion; LOZAN, Vasile; SHOFRANSKII, Valentin. Synthesis and crystal structure of a new Fe(II) α-dioximate with triazine . In: Chemistry Journal of Moldova. 2013, nr. 1(8), pp. 78-82. ISSN 1857-1727.
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Chemistry Journal of Moldova
Numărul 1(8) / 2013 / ISSN 1857-1727 /ISSNe 2345-1688

Synthesis and crystal structure of a new Fe(II) α-dioximate with triazine

Pag. 78-82

Ciobănică Olga1, Bourosh Pavlina2, Bologa Olga1, Bulhak Ion1, Lozan Vasile1, Shofranskii Valentin1
 
1 Institute of Chemistry of the Academy of Sciences of Moldova,
2 Institute of Applied Physics, Academy of Sciences of Moldova
 
Disponibil în IBN: 16 decembrie 2013


Rezumat

The interaction of [Fe(DfgH)2Py2] (where DfgH=monodeprotonated diphenylglyioxime, Py-pyridine) and 1,3,5-triazine (Trz) in chloroform resulted in a new coordination compound with the composition [Fe(DfgH)2(Trz)2]·2CHCl3 (1). The crystal structure of 1, determined by single crystal X-ray diffraction, revealed that Fe(II) atom is coordinated by four oximic nitrogen atoms of two DfgH and two nitrogen atoms of two Trz ligands resulting in octahedral surrounding.

Cuvinte-cheie
synthesis, 1, 3, crystal structure,

Fe(II)dioximate, 5-triazine

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<dc:creator>Ciobănică, O.A.</dc:creator>
<dc:creator>Bouroş, P.N.</dc:creator>
<dc:creator>Bologa, O.A.</dc:creator>
<dc:creator>Bulhac, I.I.</dc:creator>
<dc:creator>Lozan, V.I.</dc:creator>
<dc:creator>Şofransky, V.N.</dc:creator>
<dc:date>2013-02-01</dc:date>
<dc:description xml:lang='en'>The interaction of [Fe(DfgH)2Py2] (where DfgH=monodeprotonated diphenylglyioxime, Py-pyridine) and 1,3,5-triazine (Trz) in chloroform resulted in a new coordination compound with the composition [Fe(DfgH)2(Trz)2]·2CHCl3 (1). The crystal structure of 1, determined by single crystal X-ray diffraction, revealed that
Fe(II) atom is coordinated by four oximic nitrogen atoms of two DfgH and two nitrogen atoms of two Trz ligands resulting in octahedral surrounding.</dc:description>
<dc:source>Chemistry Journal of Moldova 8 (1) 78-82</dc:source>
<dc:subject>synthesis</dc:subject>
<dc:subject>Fe(II)dioximate</dc:subject>
<dc:subject>1</dc:subject>
<dc:subject>3</dc:subject>
<dc:subject>5-triazine</dc:subject>
<dc:subject>crystal structure</dc:subject>
<dc:title>Synthesis and crystal structure of a new Fe(II) α-dioximate with triazine
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