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<cfResPublDate>2012-07-02</cfResPublDate>
<cfVol>7</cfVol>
<cfIssue>2</cfIssue>
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<cfISSN>1857-1727</cfISSN>
<cfURI>https://ibn.idsi.md/ro/vizualizare_articol/22799</cfURI>
<cfTitle cfLangCode='EN' cfTrans='o'>Biomimetic strategies in organic synthesis. Terpenes</cfTitle>
<cfKeyw cfLangCode='EN' cfTrans='o'>biomimetic synthesis; cyclisation; rearrangement; oligomerisation; functionalisation.</cfKeyw>
<cfAbstr cfLangCode='EN' cfTrans='o'>The current paper represents an outline of the selected contributions to the biomimetic procedures and approaches for the synthesis of terpenes with complex structure and diverse functionalisation pattern. These include homologation strategies, cyclisations, rearrangements, as well as biomimetic remote functionalisations. Diverse groups of terpenes have been made accessible by the reported procedures: seco-eudesmanes, sacculatanes, cheilanthanes, scalaranes, rearranged labdanes and austrodoranes. Most of the presented synthetic methods represent relevant preparative value, due to the simplicity and reduced number of steps.</cfAbstr>
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