Biomimetic strategies in organic synthesis. Terpenes
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KULCIŢKI, Veaceslav. Biomimetic strategies in organic synthesis. Terpenes. In: Chemistry Journal of Moldova. 2012, nr. 2(7), pp. 46-56. ISSN 1857-1727.
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Chemistry Journal of Moldova
Numărul 2(7) / 2012 / ISSN 1857-1727 /ISSNe 2345-1688

Biomimetic strategies in organic synthesis. Terpenes

Pag. 46-56

Kulciţki Veaceslav
 
Institute of Chemistry of the Academy of Sciences of Moldova
 
Disponibil în IBN: 16 decembrie 2013


Rezumat

The current paper represents an outline of the selected contributions to the biomimetic procedures and approaches for the synthesis of terpenes with complex structure and diverse functionalisation pattern. These include homologation strategies, cyclisations, rearrangements, as well as biomimetic remote functionalisations. Diverse groups of terpenes have been made accessible by the reported procedures: seco-eudesmanes, sacculatanes, cheilanthanes, scalaranes, rearranged labdanes and austrodoranes. Most of the presented synthetic methods represent relevant preparative value, due to the simplicity and reduced number of steps.

Cuvinte-cheie
biomimetic synthesis,

cyclisation, rearrangement, oligomerisation, functionalisation.