The novel binuclear Zn(II) complex of general formula [Zn2(L)4(CH3OH)2], where L= {Cl3C(O)NP(O)(NHCH2Ph)2}- (N-[bis(benzylamino)phosphoryl]-2,2,2-trichloroacetamide), has been synthesized from a non-aqueous solution and characterized by elemental analysis, FTIR and NMR spectroscopies as well by the X-ray single crystal diffraction technique. This complex represents the third example of binuclear complexes with this ligand. It crystallizes in the triclinic P-1 space group a= 11.1197(2) Å, b= 13.3545(2) Å, c= 15.4398(3) Å, α= 106.9280(9)º, β= 90.8146(9)º, = 113.5503(9)º. The metal ion has distorted octahedral geometry; two deprotonated phosphoryl ligands in independent part are coordinated in bidentate chelate manner and joined in a dimer by the bridging oxygen atoms of the phosphoryl groups of the ligand molecules, the coordinated methanol molecule complete the coordination sphere of the central atom to six.