Kramers trimer clusters and time-reversal symmetry
Închide
Articolul precedent
Articolul urmator
330 0
SM ISO690:2012
GERU, Ion. Kramers trimer clusters and time-reversal symmetry. In: Springer Tracts in Modern Physics, 12 noiembrie 2018, Dusseldorf. Dusseldorf, Germania: Springer Verlag, 2018, Vol. 281, pp. 143-154. ISSN 00813869. DOI: https://doi.org/10.1007/978-3-030-01210-6_4
EXPORT metadate:
Google Scholar
Crossref
CERIF

DataCite
Dublin Core
Springer Tracts in Modern Physics
Vol. 281, 2018
Sesiunea "Springer Tracts in Modern Physics"
Dusseldorf, Germania, 12 noiembrie 2018

Kramers trimer clusters and time-reversal symmetry

DOI:https://doi.org/10.1007/978-3-030-01210-6_4

Pag. 143-154

Geru Ion
 
Institute of Chemistry
 
 
Disponibil în IBN: 19 iulie 2021


Rezumat

In this chapter is shown that structural distortions of trihomonuclear Kramers clusters occur as a consequence of the time-reversal symmetry. These distortions are caused by the fact that the time-reversal operator T is not a separate element of the magnetic point group G', but forms a combined T element with other g elements of the original point group G. The order of the element g cannot be an odd number, otherwise it would lead to T G', which contradicts the definition of the group G'. Forbidden rotations by (forumala Presented). in the group G' lead to the fact that metal ions of homonuclear magnetic clusters in a magnetic ordered state cannot occupy the vertices of an equilateral triangle or those of a regular pentagon. The distortion of the regular triangle or pentagon occurs only if the time-reversal operator T is taken into account. Hence these structural distortions are due to the time-reversal symmetry. There are presented and discussed experimental data concerning the anomalous behavior of chromium(II), iron(III), copper(II), vanadium(II) and cobalt(II) trihomonuclear clusters determined by their four-color symmetry.

Cuvinte-cheie
Single Molecule, Magnets, Splitting Field