Academician Pavel Vlad – a veritable scientist of our country
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2021-11-02 14:59
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54(478)(092) (46)
Chimie. Cristalografie. Mineralogie (2025)
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ARICU, Aculina. Academician Pavel Vlad – a veritable scientist of our country. In: New frontiers in natural product chemistry.: A destiny on the altar of research. Dedicated to academician Pavel Vlad, Ed. 6, 21 mai 2021, Chișinău. Chișinău, Republica Moldova: Tipografia "Artpoligraf", 2021, Ediția 6, p. 8. ISBN 978-9975-3336-7-2. DOI: https://doi.org/10.19261/nfnpc.2021.ab01
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New frontiers in natural product chemistry.
Ediția 6, 2021
Conferința " New frontiers in natural product chemistry."
6, Chișinău, Moldova, 21 mai 2021

Academician Pavel Vlad – a veritable scientist of our country

DOI:https://doi.org/10.19261/nfnpc.2021.ab01
CZU: 54(478)(092)

Pag. 8-8

Aricu Aculina
 
Institute of Chemistry
 
Proiecte:
 
Disponibil în IBN: 27 mai 2021


Rezumat

The name of the academician Pavel Vlad is associated with a number of remarkable fundamental and applied ideas. He has determined the priorities for research and some new lines in studies of terpenic compounds, in working out methods of investigation into fine organic synthesis. Under his guidance and with his direct contribution new approaches to determining the absolute configuration of a series of labdanic diterpenoids and of converting them into bi-, tri- and tetra- cyclic compounds have been designed [1]. Novel universal methods for synthesizing tetrahydrofurans from 1,4-glycols [2], olefins from tertiary alcoholic acetates, as well as dienones by means of photodehydrogenation of unsaturated cyclic ketons [3] have been developed by him. It has been established that the Swern reagent not only oxidizes the primary and secondary alcohols in the respective carbonyl compounds, but also dehydrates the tertiary alcohols [4]. The school founded by academician Pavel Vlad is the leader in the investigations of superacydic cyclisation reaction of terpenoids, and also of the regularities of the mentioned reaction in different classes of terpenic compounds, such as alcohols, their acetates, acids, esters, phenylsulphones [5]. Molecular transpositions were performed in the diterpene and sesquiterpene series [6]. Efficient ozonolytic methods for norlabdanic compounds preparation [7], as well as a new theory for evaluating the structure-ambra odor relationship have been also developed [8].