Pressure gradient effect on spin-crossover materials: Experiment vs theory
Închide
Conţinutul numărului revistei
Articolul precedent
Articolul urmator
428 0
SM ISO690:2012
RUSU, Ionela, MANOLACHE-RUSU, I. C., DIACONU, Andrei, PALAMARCIUC, Oleg, GURALSKIY, Ilya, MOLNAR, Gabor, ROTARU, Aurelian. Pressure gradient effect on spin-crossover materials: Experiment vs theory. In: Journal of Applied Physics, 2021, vol. 129, p. 0. ISSN 0021-8979. DOI: https://doi.org/10.1063/5.0042582
EXPORT metadate:
Google Scholar
Crossref
CERIF

DataCite
Dublin Core
Journal of Applied Physics
Volumul 129 / 2021 / ISSN 0021-8979 /ISSNe 1089-7550

Pressure gradient effect on spin-crossover materials: Experiment vs theory

DOI:https://doi.org/10.1063/5.0042582

Pag. 0-0

Rusu Ionela1, Manolache-Rusu I. C.1, Diaconu Andrei1, Palamarciuc Oleg23, Guralskiy Ilya45, Molnar Gabor6, Rotaru Aurelian1
 
1 „Ștefan cel Mare” University, Suceava,
2 S.C. Polivalent,
3 Moldova State University,
4 Taras Shevchenko National University of Kyiv,
5 UkrOrgSyntez Ltd., Kyiv,
6 Laboratoire de Chimie de Coordination du CNRS, Toulouse
 
 
Disponibil în IBN: 1 aprilie 2021


Rezumat

We studied the effect of non-hydrostatic pressure on the hysteretic spin crossover in coordination complexes. By introducing into an Ising-like model a double distribution of the interactions and gap energy, respectively, we were able to generate the major hysteresis loop and the first-order reversal curve (FORC) diagram for spin-crossover systems of 106 hysterons (like-spin domains). We show that, for high pressure gradients around the spin-crossover system, the thermal hysteresis loop takes an asymmetric shape, in good agreement with the experimental data on pressure effect recorded at low temperatures, below the solidification of the pressure transmitting medium. Interestingly, the FORC diagram method seems to be much more sensitive to local changes than the "bulk"parameters, which characterize the major hysteresis loop. 

Cuvinte-cheie
Coordination reactions, High pressure effects, Hydrostatic pressure, hysteresis, Hysteresis loops, pressure gradient