Growth, crystal structure, and properties of Cu2Cd1-xZnxSnS4 solid solutions
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BODNAR, Ivan V., VICTOROV, Ivan, KALITA, O., KHOROSHKO, V., ARUSHANOV, Ernest. Growth, crystal structure, and properties of Cu2Cd1-xZnxSnS4 solid solutions. In: Solid State Sciences, 2021, vol. 113, p. 0. ISSN 1293-2558. DOI: https://doi.org/10.1016/j.solidstatesciences.2021.106550
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Solid State Sciences
Volumul 113 / 2021 / ISSN 1293-2558 /ISSNe 1873-3085

Growth, crystal structure, and properties of Cu2Cd1-xZnxSnS4 solid solutions

DOI: https://doi.org/10.1016/j.solidstatesciences.2021.106550

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Bodnar Ivan V.1, Victorov Ivan2, Kalita O.1, Khoroshko V.1, Arushanov Ernest3
 
1 Belarusian State University of Informatics and Radioelectronics,
2 SSPA “Scientific and practical materials research centre of NAS of Belarus”,
3 Institute of Applied Physics
 
Disponibil în IBN: 31 martie 2021


Rezumat

The phase diagram of the Cu2CdSnS4–Cu2ZnSnS4system was constructed using data on differential thermal, X-ray phase and microstructure analysis methods. The diagram can be attributed to the first type according to the Rosebohm classification. The Cu2CdSnS4–Cu2ZnSnS4 solid solution single crystals were grown by chemical vapor transport using iodine as a transport agent. Their structure and unit cell parameters as well as compositional dependences of lattice parameters, pycnometric, X-ray densities and microhardness were determined. It was found that the Vegard's law is fulfilled in solutions studied.

Cuvinte-cheie
band gap, Cu2ZnSnS4, Cu2СdSnS4, One-temperature method, Single crystal, Solid solutions