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 SM ISO690:2012BÎRÎIAC, Andrei. Synthesis and photooxygenation of the methyl ester of 11-Homodrim-6,8(9)-diene-12-oic acid
. In: Chemistry Journal of Moldova, 2011, nr. 2(6), pp. 79-83. ISSN 1857-1727. |
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| Chemistry Journal of Moldova | ||||||
| Numărul 2(6) / 2011 / ISSN 1857-1727 /ISSNe 2345-1688 | ||||||
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| Pag. 79-83 | ||||||
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Starting with the methyl 11-homodrim-8-ene-7-oxo-12-oate a two steps synthesis of methyl-11-homodrim-6,8(9)-
diene-12-oate was accomplished in 87% overall yield, which on photooxygenation in the presence of tetraphenylporphyrin
gave a mixture of methyl esters of 11-homodrim-7-ene-6α,9α-peroxy-12-oic and 11-homodrim-5,8-diene-7-oxo-12-oic
acids 21% and 54% yields, respectively.
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| Cuvinte-cheie homodrimanes, photooxygenation, synthesis |
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