| Conţinutul numărului revistei |
| Articolul precedent |
| Articolul urmator |
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 998 16 |
| Ultima descărcare din IBN: 2024-03-09 15:47 |
| Căutarea după subiecte similare conform CZU |
| 547-326+547.271 (1) |
| Chimie organică (501) |
 SM ISO690:2012CIOCARLAN, Alexandru, LUNGU, Lidia, BLAJA, Svetlana, DRAGALIN, Ion, ARICU, Aculina. The use of some non-conventional methods in chemistry of bicyclohomofarnesenic methyl esters. In: Chemistry Journal of Moldova, 2020, nr. 2(15), pp. 69-77. ISSN 1857-1727. DOI: https://doi.org/10.19261/cjm.2020.791 |
| EXPORT metadate: Google Scholar Crossref CERIF DataCite Dublin Core |
  Chemistry Journal of Moldova |
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| Numărul 2(15) / 2020 / ISSN 1857-1727 /ISSNe 2345-1688 | |||||||||
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| DOI:https://doi.org/10.19261/cjm.2020.791 | |||||||||
| CZU: 547-326+547.271 | |||||||||
| Pag. 69-77 | |||||||||
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| Rezumat | |||||||||
The main purpose of this research was to prove the utility of some non-conventional methods in synthesis of new and known homodrimanic compounds. Three methods belonging to green chemistry were successfully used in reported transformations. As a result of microwave irradiation assisted method the formation of bicyclohomofarnesenic methyl esters versus classical Stoll and Hinder method was studied. By means of anodic oxidation and dye-sensitized photooxidation of mentioned esters series of new compounds were obtained and the mechanism of some products formation was established. In addition, new pathway for the preparation of methyl 7-oxo-13,14,15,16-tetranorlabd-6,8(8)-dien-12-oate was elaborated. The structure of all synthesized compounds was fully confirmed by spectral methods. |
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| Cuvinte-cheie bicyclohomofarnesenic methyl ester, microwave irradiation, anodic electrooxidation, dye-sensitized photooxidation |
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