| Conţinutul numărului revistei |
| Articolul precedent |
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 SM ISO690:2012OSTROVSKY, Sergei M.. Magnetostructural study of four-coordinated Co(II) complexes with mixed ligand surrounding. In: Polyhedron, 2021, nr. 194, p. 0. ISSN 0277-5387. DOI: https://doi.org/10.1016/j.poly.2020.114936 |
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  Polyhedron |
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| Numărul 194 / 2021 / ISSN 0277-5387 /ISSNe 1873-3719 | ||||||
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| DOI:https://doi.org/10.1016/j.poly.2020.114936 | ||||||
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The dependence of the zero-field splitting parameters on the structural modification of the nearest ligands surrounding in the [CoCl2L2] complexes (with L being the N-donor ligand) is studied. The modification was modeled by the variations of the NCoN and ClCoCl angles, by the rotation of the chlorido ligands with respect to other ligand groups as well as by the strength of the N-donor ligands. The found tendency was compared with the experimental data for this type of cobalt complexes known from literature. |
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| Cuvinte-cheie Crystal field theory, Four-coordinated, Co(II), Magnetic anisotropy, Magnetostructural correlation, Zero-field splitting |
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