Because of their promising sorption, magnetic, optical and other physical properties metalorganic frameworks (MOF) attract much attention for the development of the new generation of functional materials. The topologies of the crystal lattices of these solids are determined primarily by the coordinative interaction between the metal centers (nodes) and organic ligands (bridges). Usage of functionalized azamacrocyclic complexes (i.e., complexes bearing additional substituents in the macrocyclic backbone with donor or acceptor group) offers new possibilities for rational design of MOF. Recently, we have developed a convenient one-pot template procedure for the preparation of 3-pyridyl-substituted macrocyclic copper(II) complex [CuL]2+. Single crystal X-ray analysis evidenced dimeric structure of the complex [CuL(H2O)(ClO4)](ClO4) with H-bond formed between aromatic nitrogen and water molecule coordinated to the metal ion. Depending on the reaction conditions two single crystalline products were obtained from the reaction of [CuL]2+ with 1,3,5-benzenetricarboxylate (btc), namely, {Cu[CuL)(H2O)2](btc)}(btc)0,33·6H2O and [CuL(H2O)2][(CuL)2(btc)2]·2H2O.