| Articolul precedent |
| Articolul urmator |
 |
 668 1 |
| Ultima descărcare din IBN: 2021-07-16 16:59 |
 SM ISO690:2012COCU, Maria, DRUŢĂ, Vadim, REVENKO, M., STAVROPOULOS, P.. Synthesis, investigation, and catalytic behavior of some new Fe(III) Schiff-type complexes. In: Physical Methods in Coordination and Supramolecular Chemistry, 27 septembrie - 1 octombrie 2006, Chişinău. Chisinau, Republic of Moldova: 2006, XVII, p. 113. ISBN 978-9975-62-066-6. |
| EXPORT metadate: Google Scholar Crossref CERIF DataCite Dublin Core |
| Physical Methods in Coordination and Supramolecular Chemistry XVII, 2006 |
||||||
|
Conferința "The XV-th International Conference Physical Methods in Coordination and Supramolecular Chemistry : The XVII-th Reading in memory of Acad. A.Ablov" Chişinău, Moldova, 27 septembrie - 1 octombrie 2006 | ||||||
|
||||||
| Pag. 113-113 | ||||||
|
||||||
 Descarcă PDF |
||||||
| Rezumat | ||||||
Here we report the synthesis of a series of new iron(III) coordination compounds on the base of tridentate ligand, mono-(S-methylisothiosemicarbazone) of 1-hydroxi-2-naphtaldehyde (H2L):formulaBy interaction of corresponding iron(III) salts with the H2L ligand, in methanol or ethanol solutions, were obtained four new coordination compounds with following compositions: Fe(HL)L (1); [Fe(HL)2]X (where X = Cl (2), NO3 (3)) and [FeHL]Cl2 (4). All these complexes are isolated from solutions as black microcrystalline samples. The structure and composition of these compounds were investigated using various physical methods of analysis. It was shown, that the complexes act as pre-catalysts in the reactions of catalytic oxidation of adamantane under Gif – type conditions. The oxidation of adamantane by these systems provided complete product profiles (1-adamantanol and 2-adamantanol, 2-adamantanone, and four adamantylpyridines), suggesting a radical mechanism of adamantane oxidation, as previously observed in Gif chemistry. |
||||||
|
|
|
|
