This report is devoted to the generalization of research considered the physical-chemical properties and directed functionalization methods of linear oligopyrroles (dipyrrines and their bis-derivatives), their complexes and hybrid materials based on them for solving different theoretical and practical tasks. Differing several intramolecular or extramolecular parameters (the structure of di- and tetrapyrrolic ligand or they complexes with a large variety of metals; the nature of solvent media (in solutions) or polymeric matrices (in hybrid material) is a very effective instrument for searching of practically useful materials for optic, medicine, nanotechnologies. Linear oligopyrroles metal complexes are the great example of compounds combining high flexibility of aromatic π-system of pyrrole rings with linkers and the ability to form very kinetically and thermodynamically stable six-member metallocycles. A wide variety for constructing different types of complexes (homo- and heteroleptic, mono- and polynuclear) allowing us to accurately tune the spectral and photo-physical properties of investigated compounds under the exact task. The methods of hybrid material synthesis by incorporation of investigated compounds into organic or inorganic polymeric matrices with the formation of spatial grid which differs from the initial structures but saving common motives and functionality are especially effective.