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SM ISO690:2012 MACSIM, Ana-Maria, GEORGESCU, Emilian I., GEORGESCU, Florentina, DUMITRASCU, Florea, DRAGHICI, Constantin C., NICOLESCU, Alina Florica, DELEANU, Călin. Multicomponent synthesis and NMR characterization of benzo[f]pyrrolo[1,2-a] quinoline derivatives. In: Achievements and perspectives of modern chemistry, 9-11 octombrie 2019, Chişinău. Chisinau, Republic of Moldova: Tipografia Academiei de Ştiinţe a Moldovei, 2019, p. 228. ISBN 978-9975-62-428-2. |
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Achievements and perspectives of modern chemistry 2019 | |
Conferința "International Conference "Achievements and perspectives of modern chemistry"" Chişinău, Moldova, 9-11 octombrie 2019 | |
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Pag. 228-228 | |
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Benzo[f]pyrrolo[1,2-a]quinoline is a fused ring system with a bridgehead nitrogen atom structurally similar to the steroid skeletonand its derivatives show potential biological activity and interesting features of dyes. Benzo[f]pyrrolo[1,2-a]quinoline derivatives have been prepared via multistep synthesis from 1-hydroxy-8-methoxybenzo[f]quinoline, by 1,3-diploar cycloaddition reactions of benzo[f]quinolinium N-ylides with acetylenic dipolarophiles,or by the cascade reactions of N-(naphthalen-2-yl)pent-4-ynamides with arylacetylenes under microwave irradiation in the presence of AuBr3-AgSbF6 catalyst system. We present an efficient one-pot, three component microwave-assisted synthesis of a range of novel benzo[f]pyrrolo[1,2-a]quinoline derivatives,which has the advantages of considerable shorter reaction time, reduced solvent consumption, operational simplicity and minimal impact on the environment.formula |
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