| Conţinutul numărului revistei |
| Articolul precedent |
| Articolul urmator |
 956 0 |
 SM ISO690:2012COROPCEANU, Eduard, RUDIK, V., CEPOI, Liliana, RUDI, Ludmila, LOZAN, Vasile, CHIRIAC, Tatiana, MISCU, Vera, BULHAK, Ion, KRAVTSOV, Victor, BOUROSH, Pavlina. Synthesis and Crystal Structure of [Co(DmgH) 2 (Thio) 2 ] 2 F[PF 6 ]. The Effect of Fluorine-Containing Co(III) Dioximates on the Physiological Processes of the Microalga Porphyridium cruentum. In: Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 2019, vol. 45, pp. 200-207. ISSN -. DOI: https://doi.org/10.1134/S1070328419030059 |
| EXPORT metadate: Google Scholar Crossref CERIF DataCite Dublin Core |
  Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya |
||||||
| Volumul 45 / 2019 / ISSN - /ISSNe 1070-3284 | ||||||
|
||||||
| DOI:https://doi.org/10.1134/S1070328419030059 | ||||||
| Pag. 200-207 | ||||||
|
||||||
| Rezumat | ||||||
Abstract: New fluorine-containing cobalt(III) dioximates [Co(DmgH) 2 (Thio) 2 ] 2 F[PF 6 ] (I) and [Co(DmgH) 2 (Sam) 2 ] 2 [TiF 6 ] · 4H 2 O (II) (DmgH = dimethylglyoxime monoanion, Thio = thiourea, Sam = sulfanilamide) were obtained. The structure of I was determined by X-ray diffraction (CIF file CCDC no. 1852216). The crystals are cubic, space group (Formula Presented.). The octahedral coordination polyhedron of the metal is formed by the N 4 S 2 set of donor atoms of two DmgH¯ ligands and two Thio molecules. The effect of compounds I and II and two previously described compounds of this class with fluorine anions, [Co(DmgH) 2 (Thio) 2 ] 2 [TiF 6 ] · 2H 2 O (III) and [Co(DmgH) 2 (An) 2 ] 2 [ZrF 6 ] (IV) (An = aniline), on the physiological processes of the red microalga Porphyridium cruentum was studied. Complex III in concentration of 20 mg/L increased the microalga productivity by 20% and lipid biosynthesis by 17% and can be proposed for biotechnology applications. |
||||||
| Cuvinte-cheie biomass accumulation, Co(III) dioximatescrystal structure, lipid synthesis, red microalga, Porphyridium cruentum |
||||||
|
|
|
|
