| Conţinutul numărului revistei |
| Articolul precedent |
| Articolul urmator |
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 1017 17 |
| Ultima descărcare din IBN: 2023-04-19 17:44 |
| Căutarea după subiecte similare conform CZU |
| 546.72/.74 (1) |
| Inorganic chemistry (450) |
 SM ISO690:2012CUZAN, Olesea, MELNYK, Silvia, SHOVA, Sergiu. Synthesis and X-ray characterisation of a new mixed-valence trinuclear iron cluster. In: Chemistry Journal of Moldova, 2018, nr. 2(13), pp. 48-55. ISSN 1857-1727. DOI: https://doi.org/10.19261/cjm.2018.504 |
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  Chemistry Journal of Moldova |
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| Numărul 2(13) / 2018 / ISSN 1857-1727 /ISSNe 2345-1688 | ||||||
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| DOI:https://doi.org/10.19261/cjm.2018.504 | ||||||
| CZU: 546.72/.74 | ||||||
| Pag. 48-55 | ||||||
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| Rezumat | ||||||
This paper reports on the synthesis of a new trinuclear homometalic mixed-valence iron carboxylate cluster with furan-2-carboxylic acid. The complex with the formula [Fe2IIIFeIIO(C4H3OCOO)6(H2O)3]∙0.5CH3CN·2.25H2O was characterized by X-ray analysis that revealed that the compound crystalizes in the triclinic centrosymmetric group P-1, with the following unit cell parameters: a= 10.2758(6) Å, b= 11.5991(9) Å, c= 19.7349(15) Å, α= 105.060(7)°, β= 94.216(6)°, γ= 101.662(6)°. |
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| Cuvinte-cheie iron cluster, mixed valence, X-ray analysis, μ3-oxo, crystal structure, hydrogen bond. |
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