Synthesis and characterisation of a novel phosphonate ligand and its palladium(II) coordination compound
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2022-10-19 12:25
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541.128+546.98 (1)
Chemistry. Crystallography. Mineralogy (2025)
Inorganic chemistry (450)
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CUZAN, Olesea. Synthesis and characterisation of a novel phosphonate ligand and its palladium(II) coordination compound. In: Chemistry Journal of Moldova, 2017, vol. 12, pp. 74-80. ISSN 1857-1727. DOI: https://doi.org/10.19261/cjm.2016.370
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Chemistry Journal of Moldova
Volumul 12 / 2017 / ISSN 1857-1727 /ISSNe 2345-1688

Synthesis and characterisation of a novel phosphonate ligand and its palladium(II) coordination compound
DOI:https://doi.org/10.19261/cjm.2016.370
CZU: 541.128+546.98

Pag. 74-80

Cuzan Olesea12
 
1 Institute of Chemistry of the Academy of Sciences of Moldova,
2 Université d’Aix-Marseille
 
 
Disponibil în IBN: 15 august 2017


Rezumat

The novel N-(methylene-2-pyridine)-N,N-bis(diethoxyphosphorylmethyl)amine ligand (L) was obtained through a double Kabachnik-Fields reaction, starting from 2-(aminomethyl)pyridine (2-picolylamine). Based on the L ligand, a new palladium(II) coordination compound [Pd(L)2Cl2] has been synthesized and comprehensively characterized by spectroscopic methods (1H NMR, UV-Vis), ESI mass spectrometry and X-ray crystallography.

Cuvinte-cheie
palladium, coordination compounds,

phosphonate ligands, X-ray characterisation