Synthesis and crystal structure of a new Fe(II) α-dioximate with triazine

Covaci (Ciobănică) Olga; Bourosh Pavlina; Bologa Olga; Bulhak Ion; Lozan Vasile; Shofransky Valentin

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2015-12-03 17:45

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COVACI (CIOBĂNICĂ), Olga, BOUROSH, Pavlina, BOLOGA, Olga, BULHAK, Ion, LOZAN, Vasile, SHOFRANSKY, Valentin. Synthesis and crystal structure of a new Fe(II) α-dioximate with triazine . In: Chemistry Journal of Moldova, 2013, nr. 1(8), pp. 78-82. ISSN 1857-1727.

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Chemistry Journal of Moldova

Numărul 1(8) / 2013 / ISSN 1857-1727 /ISSNe 2345-1688

Synthesis and crystal structure of a new Fe(II) α-dioximate with triazine

Pag. 78-82

Covaci (Ciobănică) Olga¹, Bourosh Pavlina², Bologa Olga¹, Bulhak Ion¹, Lozan Vasile¹, Shofransky Valentin¹

¹ Institute of Chemistry of the Academy of Sciences of Moldova,
² Institute of Applied Physics, Academy of Sciences of Moldova

Disponibil în IBN: 16 decembrie 2013

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The interaction of [Fe(DfgH)2Py2] (where DfgH=monodeprotonated diphenylglyioxime, Py-pyridine) and 1,3,5-triazine (Trz) in chloroform resulted in a new coordination compound with the composition [Fe(DfgH)2(Trz)2]·2CHCl3 (1). The crystal structure of 1, determined by single crystal X-ray diffraction, revealed that Fe(II) atom is coordinated by four oximic nitrogen atoms of two DfgH and two nitrogen atoms of two Trz ligands resulting in octahedral surrounding.

Cuvinte-cheie
synthesis, 1, 3, crystal structure,

Fe(II)dioximate, 5-triazine

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