Hydrophilization of the pyrolysis residue of tires to obtain watermiscible pigments
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66.01-52:678.4+541.6 (1)
Chemical technology. Chemical and related industries (1502)
Industries based on macromolecular materials. Rubber industry. Plastics industry (50)
Chemistry. Crystallography. Mineralogy (2025)
SM ISO690:2012
PETUHOV, Oleg, TIMBALIUC, Nina, VITIU (BOLDIŞOR), Aliona, CEBAN (GÎNSARI), Irina, CEBOTARI, Irina. Hydrophilization of the pyrolysis residue of tires to obtain watermiscible pigments. In: Central and Eastern European Conference on Thermal Analysis and Calorimetry: and 14th Mediterranean Conference on Calorimetry and Thermal Analysis, Ed. 5, 28-31 august 2017, Chişinău. Roma, Italy: Academica Greifswald, 2019, Editia 5, p. 309. ISBN 978-3-940237-59-0.
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Central and Eastern European Conference on Thermal Analysis and Calorimetry
Editia 5, 2019
Conferința "Central and Eastern European Conference on Thermal Analysis and Calorimetry"
5, Chişinău, Moldova, 28-31 august 2017

Hydrophilization of the pyrolysis residue of tires to obtain watermiscible pigments

CZU: 66.01-52:678.4+541.6

Pag. 309-309

Petuhov Oleg1, Timbaliuc Nina1, Vitiu (Boldişor) Aliona12, Ceban (Gînsari) Irina1, Cebotari Irina1
 
1 Institute of Chemistry,
2 Institute of Applied Physics
 
 
Disponibil în IBN: 9 iunie 2020


Rezumat

Pyrolysis is a widespread recycling technology of polymeric waste. Used tires being pyrolysis lead to the formation of three components: fuel fraction which being subjected to purification to yield gasoline and diesel fuel, steel wire which is recycled and carbon black that is accumulated contaminating the environment. This is explained by the specific properties of carbon black: small, hydrophobic particles that easily disperse and pollute the environment, is a possible carcinogen for humans, and short-term exposure to high concentrations can cause discomfort in the upper respiratory tract. At the same time, the carbon black obtained from tire pyrolysis contains a significant amount of fuel and is not miscible in polar solvents such as water. This makes the field of use of carbon black is narrow - is needed remove adsorbed fuel from particles and render them hydrophilic properties, thus obtaining a black pigment, the fields of use of which substantially increase: pigment for the production of pavement, decorative mortar, lacquers and paints, supplement for construction and repair of road. Studied tire pyrolysis residue is a homogeneous, finely dispersed, water-immiscible black substance. In order to assess the thermal stability of the residue, thermal analysis was performed in a dynamic air atmosphere. The results of thermal analysis show that the residue is stable up to 320 oC and total thermal degradation takes place at 750 oC, the carbon black begins to lose weight as soon as heating begins, the process continuing at temperatures above 300 °C; this is explained by the increased content of volatile substances that have not been completely discharged during pyrolysis. From thermal analysis was established that the carbon black contains 15% flammable volatile substances, oxygen oxidation of the surface in the air begins at 320 oC and total degradation takes place at temperatures above 430 oC. As a result of thermal degradation of soot no solid residue is formed. Based on the results of the thermal analysis, preventive degassing of the soot at 200-250 oC is recommended for evacuate volatile substances to prevent their accumulation and explosion. Oxidation with air is recommended to be carried out at 350-400 oC by continuous mixing to obtain a homogeneous product.