Novel CU(II) dimers with ferromagnetic intra- and intermolecular exchange interactions

Uraev Ali; Vasilchenko I.; Ikorskii V.; Shestakova T.; Burlov A.; Lyssenko K.; Vlasenko V.; Kuzmenko T.; Divaeva L.; Pirog I.; Borodkin G.; Uflyand I.; Antipin Mikhail; Ovcharenko V.; Garnovskii Alexander; Minkin V.

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URAEV, Ali, VASILCHENKO, I., IKORSKII, V., SHESTAKOVA, T., BURLOV, A., LYSSENKO, K., VLASENKO, V., KUZMENKO, T., DIVAEVA, L., PIROG, I., BORODKIN, G., UFLYAND, I., ANTIPIN, Mikhail, OVCHARENKO, V., GARNOVSKII, Alexander, MINKIN, V.. Novel CU(II) dimers with ferromagnetic intra- and intermolecular exchange interactions. In: Чугаевская конференция по координационной химии, 20-24 iunie 2005, Chişinău. Chișinău, Republica Moldova: Tipografia Academiei de Ştiinţe a Moldovei, 2005, p. 272.

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Чугаевская конференция по координационной химии 2005

Conferința "Чугаевская конференция по координационной химии"
Chişinău, Moldova, 20-24 iunie 2005

Novel CU(II) dimers with ferromagnetic intra- and intermolecular exchange interactions

Pag. 272-272

Uraev Ali¹², Vasilchenko I.¹², Ikorskii V.³, Shestakova T.⁴, Burlov A.¹², Lyssenko K.⁵, Vlasenko V.⁶, Kuzmenko T.¹, Divaeva L.¹, Pirog I.⁶, Borodkin G.¹, Uflyand I.⁴, Antipin Mikhail⁵, Ovcharenko V.³, Garnovskii Alexander¹², Minkin V.¹²

¹ Research Institute of Physical and Organic Chemistry, Rostov State University of Rostov-on-Don,,
² South Scientific Center of Russian Academy of Science,
³ International Tomography Center, Siberian Branch of the RAS,
⁴ Rostov State Pedagogical University,
⁵ A.N.Nesmeyanov Institute of Organoelement Compounds of RAS,
⁶ Rostov State University

Disponibil în IBN: 29 mai 2020

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Teza

Fragment annelated to the polymetallic core in binuclear copper complexes
of tridentate bibasic aromatic and heterocyclic N3, N2S, NOS donor ligands could
essentially change both steric and electronic structure of an exchange cluster.
The reconstruction of an exchange cluster provoked by a fragment annelated to
the spin coupled system is able to change the sign of J.
Authors are grateful to Integrated Program of Presidium of Russian Academy
of Sciences “Directed Synthesis of Compounds with Adjusted Properties and
Creation of Functional Materials on their Base” (grant 00-04-17), Ministry of
Education and Science of Russian Federation (grant NS-945.2003.3), Russian
Foundation for Basic Research (grants 03-03-32842, 04-03-32366) and BRHE
(NO-008-X1) for the financial support.