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 SM ISO690:2012KLOKISHNER, Sophia I., LINARES, Jorge. Effects of intra- And intercenter interactions in spin crossover: Application of the density matrix method to the nonequilibrium low-spin↔High-spin transitions induced by light. In: Journal of Physical Chemistry C, 2007, vol. 111, pp. 10644-10651. ISSN 1932-7447. DOI: https://doi.org/10.1021/jp070126j |
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  Journal of Physical Chemistry C |
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| Volumul 111 / 2007 / ISSN 1932-7447 /ISSNe 1932-7455 | ||||||
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| DOI:https://doi.org/10.1021/jp070126j | ||||||
| Pag. 10644-10651 | ||||||
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A microscopic model of nonequilibrium light-induced phase transitions in spin crossover systems based on the solution of the equations for the density operator is developed. The conditions of light-induced and thermally induced bistability are revealed. The results are compared with those obtained in the framework of the Glauber's approach. The qualitative explanation of experimental data on a series of spin crossover systems is given. |
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| Cuvinte-cheie Engineering controlled terms Density (specific gravity), mathematical models, Microscopic examination, phase equilibria, Spin dynamics, Thermal effects Engineering uncontrolled terms Density matrix, High spin transitions, Microscopic models, Spin crossover systems Engineering main heading Molecular interactions |
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